Electric current is defined as the net rate of flow of electric charge across any cross-section of a conductor. If a net charge \(\Delta q\) flows across a cross-section in time \(\Delta t\), the instantaneous electric current is given by:
Although electric current possesses both magnitude and direction (the direction of conventional current is opposite to the drift of electrons), it is a scalar quantity because it follows ordinary laws of algebra rather than vector addition. In contrast, current density (\(\vec{J}\)) is a vector quantity defined as the current per unit cross-sectional area oriented normal to the flow of charge:
The SI unit of electric current is Ampere (\(\text{A} = \text{C/s}\)), and that of current density is \(\text{A/m}^2\).
In the absence of an applied electric field, conduction electrons inside a metallic conductor execute random thermal motion with speeds of the order of \(10^5 \text{ to } 10^6 \text{ m/s}\), undergoing frequent elastic collisions with vibrating positive lattice ions. Because this motion is completely isotropic, the average thermal velocity of all electrons is zero:
When an external electric field \(\vec{E}\) is established across the conductor (by maintaining a potential difference \(V\) across length \(l\)), each electron experiences an electrostatic force \(\vec{F} = -e\vec{E}\), giving rise to an acceleration \(\vec{a} = -\frac{e\vec{E}}{m}\). In between successive lattice collisions, an electron accelerates. If \(\tau_i\) represents the time elapsed since the last collision for the \(i\)-th electron (called the relaxation time), its velocity becomes:
Averaging over all \(N\) free electrons yields the drift velocity (\(\vec{v}_d\)):
where \(\tau\) is the mean relaxation time (typically \(10^{-14} \text{ s}\) at room temperature). The drift velocity is remarkably slow—of the order of \(10^{-4} \text{ to } 10^{-3} \text{ m/s}\) (a fraction of a millimeter per second).
Consider a conductor of cross-sectional area \(A\) containing \(n\) free electrons per unit volume. In time \(\Delta t\), electrons moving with drift speed \(v_d\) traverse a distance \(\Delta x = v_d \Delta t\). The volume of this cylindrical section is \(A v_d \Delta t\), and the total charge flowing across the cross-section is:
Dividing by cross-sectional area \(A\) yields the current density:
Comparing this with the microscopic statement of Ohm's law, \(\vec{J} = \sigma \vec{E}\), we identify the electrical conductivity (\(\sigma\)) and resistivity (\(\rho\)):
Electron mobility (\(\mu\)) is defined as the magnitude of drift velocity acquired per unit applied electric field:
The SI unit of mobility is \(\text{m}^2 \cdot \text{V}^{-1} \cdot \text{s}^{-1}\) (or \(\text{m}^2 / (\text{V} \cdot \text{s})\)). In semiconductors, both electrons and holes contribute to total conductivity: \(\sigma = e(n_e \mu_e + n_h \mu_h)\).